[發明專利]一種空心管狀聚吡咯膜的制備方法

有效

• 申請號: 201410325427.9
• 申請日: 2014-07-10
• 公開（公告）號: CN104072768A
• 公開（公告）日: 2014-10-01
• 發明（設計）人: 李梅;楊蘭蘭;張云強
• 申請（專利權）人: 齊魯工業大學
• 主分類號: C08G73/06
• 分類號: C08G73/06;C08L79/04
• 代理公司: 暫無信息
• 代理人: 暫無信息

技術領域

本發明涉及一種導電聚合物膜的制備方法，屬于導電聚合物薄膜材料制備技術領域。

背景技術

導電高分子擁有電學、電化學、力學、光學、磁學等諸多優良性質，在生產生活、軍事、航空航天等領域都具有潛在的應用前景。導電高分子材料的形貌和尺寸對聚合物的電性能、氣敏傳感性能、催化性能產生重要的影響，因此導電聚合物形貌的可控合成，成為導電高分子合成領域的研究熱點和難點（Yongqiang?Yang,?Ruiqing?Pang,?Xuejiao?Zhou,?Yan?Zhang,?Haixia?Wu?and?Shouwu?Guo,?Composites?of?chemically-reduced?graphene?oxide?sheets?and?carbon?nanospheres?with?three-dimensional?network?structure?as?anode?materials?for?lithium?ion?batteries,?J.?Mater.?Chem.,?2012,?22,?23194–23200.?S.?N.?Beesabathuni,?J.?G.?Stockham,?J.?H.?Kim,?H.?B.?Lee,?J.?H.?Chung?and?A.?Q.?Shen,?Fabrication?of?conducting?polyaniline?microspheres?using?droplet?microfluidics,?RSC?Adv.,?2013,?3,?24423–24429,?Byoung?Hoon?Lee?,Jong-Hoon?Lee?,Yung?Ho?Kahng?,Nara?Kim?,Yong?Jae?Kim?,Jongjin?Lee?,Takhee?Lee?,?Kwanghee?Lee,?Graphene-Conducting?Polymer?Hybrid?Transparent?Electrodes?for?Efficient?Organic?Optoelectronic?Devices,?Adv.?Funct.?Mater.?DOI:?10.1002/adfm.201302928），以表面活性劑為軟模板能夠制備出顆粒狀、纖維狀以及管狀的導電聚吡咯，由于其形貌和結構的差異，這些導電聚合物在電導率、超級電容器材料以及鋰離子電池材料表現出優異的性能（Xuehua?Zhang,?Shasha?Wang,?Shan?Lu,?Jia?Su,?Tao?He,?Influence?of?doping?anions?on?structure?and?properties?of?electro-polymerized?polypyrrole?counter?electrodes?for?use?in?dye-sensitized?solar?cells,?J.?Power?Sources,?246?(2014)?491-498,?Weiyang?Li,?Qianfan?Zhang,?Guangyuan?Zheng,?Zhi?Wei?Seh,?Hongbin?Yao,?Yi?Cui,?Understanding?the?Role?of?Different?Conductive?Polymers?in?Improving?the?Nanostructured?Sulfur?Cathode?Performance,?Nano?Lett.2013,?13,?5534?5540,?Oleg?Yu?Posudievsky,?Olga?A.?Kozarenko,?Vyacheslav?S.?Dyadyuna,?Scott?W.?Jorgensen,?James?A.?Spearot,?Vyacheslav?G.?Koshechko,?Vitaly?D.?Pokhodenko,?Mechanochemically?prepared?ternary?hybrid?cathode?material?for?lithium?batteries,?Electrochim.?Acta.?109?(2013)?866–873,?Qian?Liu,?Zonghua?Pu,?ChunTang,?Abdullah?M.?Asiri,?Abdullah?H.?Qusti,?Abdulrahman?O.?Al-Youbi,?Xuping?Sun,?N-doped?carbon?nanotubes?from?functional?tubular?polypyrrole:?A?highly?efficient?electrocatalyst?for?oxygen?reduction?reaction,?Electrochem.?Commun.?36?(2013)?57–61）。以甲基橙為模板制備出的管狀聚吡咯微/納米管電導率達到33.0S/cm,?溶解性能略有改善（Juan?Li,?Li?Cui,?Xiaogang?Zhang,?Preparation?and?electrochemistry?of?one-dimensional?nanostructured?MnO2/PPy?composite?for?electrochemical?capacitor,?Applied?Surface?Science?256?(2010)?4339–4343,?Suk?Fun?Chin,?Suh?Cem?Pang,?Tetrapropylammonium-manganese?oxide/polypyrrole?hybrid?nanocomposite?thin?films?as?novel?electrode?materials?for?supercapacitors,?Materials?Chemistry?and?Physics124?(2010)?29–32,?J.?Upadhyay,?A.?Kumar,?Structural,?thermal?and?dielectric?studies?of?polypyrrole?nanotubes?synthesized?by?reactive?self?degrade?template?method,?Materials?Science?and?Engineering?B?178?(2013)?982–989）。聚吡咯薄膜的電容性能更佳（Xiao?Du,?Xiaogang?Hao,?Zhongde?Wang,?Xuli?Ma,?Guoqing?Guan,?Abudula?Abuliti,?Guozhang?Ma,?Shibin?Liu,?Highly?stable?polypyrrole?film?prepared?by?unipolar?pulse?electro-polymerization?method?as?electrode?for?electrochemical?supercapacitor,?Synthetic?Metals?175?(2013)?138–145,?Sujata?S.?Shinde,?Girish?S.?Gunda,?Deepak?P.?Dubalb,?Supriya?B.?Jambure,?Chandrakant?D.?Lokhande,?Morphological?modulation?of?polypyrrole?thin?films?through?oxidizing?agents?and?their?concurrent?effect?on?supercapacitor?performance,?Electrochimica?Acta?119?(2014)?1–10,?B.?H.?Patil,?R.?N.?Bulakhe,?C.?D.?Lokhande,?Supercapacitive?performance?of?chemically?synthesized?polypyrrole?thin?films:?effect?of?monomer?to?oxidant?ratio,?J?Mater?Sci:?Mater?Electron?(2014)?25:2188–2198）。以甲基橙作為軟模板來制備導電聚吡咯膜尚未有報道。